Synthesis of N-Acetylglucosamine Aryl β-Glycosides Catalyzed by Crown Compounds

VO Kur'yanov, TA Chupakhina, AE Zemlyakov…

Index: Kur'yanov; Chupakhina; Zemlyakov; Kotlyar; Kamalov; Chirva Russian Journal of Bioorganic Chemistry, 2001 , vol. 27, # 6 p. 385 - 389

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Citation Number: 11

Abstract

Abstract Glycosylation of various phenols with α-D-glucosaminyl chloride peracetate in a solid phase–liquid system catalyzed by crown compounds was studied. The highest yields of aryl β-glycosides were observed at room temperature in acetonitrile using anhydrous potassium carbonate as a base. The optimum phenol–glycosyl donor–base–crown ether ratio was 1: 1: 1: 0.2.