Elucidating the Mechanism of the Halide-Induced Ligand Rearrangement Reaction

…, AM Brown, MJ Wiester, CL Stern, CA Mirkin

Index: Wiester, Michael J.; Braunschweig, Adam B.; Yoo, Hyojong; Mirkin, Chad A. Inorganic Chemistry, 2010 , vol. 49, # 15 p. 7188 - 7196

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Citation Number: 8

Abstract

The Halide-Induced Ligand Rearrangement (HILR) reaction results in the quantitative yield of heteroligated complexes. Several key intermediates have been identified via 31P {1H} NMR spectroscopy and single-crystal X-ray diffraction studies. In addition, the roles of the