Catalytic, Highly Regio??and Chemoselective Generation of Radicals from Epoxides: Titanocene Dichloride as an Electron Transfer Catalyst in Transition Metal …

A Gansäuer, M Pierobon…

Index: Gansaeuer, Andreas; Pierobon, Marianna; Bluhm, Harald Angewandte Chemie - International Edition, 1998 , vol. 37, # 1-2 p. 101 - 103

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Citation Number: 156

Abstract

Abstract Sensitive functional groups like halides, ketones, or tosylates pose no difficulties in the new,[Cp 2 TiCl 2]-catalyzed, radical reaction [Eq.(1)]. The conversions proceed with excellent chemoselectivity, which in many cases is complementary to that of established reactions.