Synthesis and crystal structure of 5, 7-diallyloxy-4-methylcoumarin

…, VK Gupta, BD Gupta, K Sivakumar

Index: Goswami, Sanjeev; Gupta, Vivek K.; Gupta; Sivakumar Journal of Chemical Crystallography, 2006 , vol. 36, # 1 p. 77 - 82

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Citation Number: 3

Abstract

The title compound, 5, 7-diallyloxy-4-methyl-2 H-1-benzopyran-2-one,(C 16 H 16 O 4), was prepared by condensation of ethyl acetoacetate with phloroglucinol followed by allylation of the 5, 7-dihydroxy-4-methylcoumarin thus obtained. The compound crystallizes into monoclinic space group P 2 1/c with unit cell parameters a= 7.531 (1) Å, b= 22.596 (4) Å, c= 8.090 (1) Å, β= 92.74 (2)°, Z= 4. The crystal structure was solved by direct methods using ...