Attempts to generate diphenylcyclopropenylidene. IV

WM Jones, ME Stowe, EE Wells Jr…

Index: Jones,W.M. et al. Journal of the American Chemical Society, 1968 , vol. 90, # 7 p. 1849 - 1859

Full Text: HTML

Citation Number: 39

Abstract

Abstract: Attempts have been made to generate the potentially nucleophilic carbene, 2, 3- diphenylcyclopropenyli-dene, and the corresponding diphenyldiazocyclopropene. The methods explored include oxidation of the hydrazone, decomposition of salts of the tosylhydrazone, reaction of the appropriate N-nitrosocarbamate with base, and a eliminations of carboxylic acids from the diphenylcyclopropenyl acetate, benzoate, p- ...