Synthesis and characterization of new 2-pyrimidyl chalcogen (S, Se, Te) compounds: X-ray crystal structure of bis (4, 6-dimethyl-2-pyrimidyl) diselenide and 4, 6- …

KK Bhasin, E Arora, AS Grover, H Singh…

Index: Bhasin; Arora, Ekta; Grover, Alka S.; Jyoti; Singh; Mehta; Bhasin, Aman K.K.; Jacob Journal of Organometallic Chemistry, 2013 , vol. 732, p. 137 - 141

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Citation Number: 2

Abstract

New and synthetically important symmetrical bis (4, 6-dimethyl-2-pyrimidyl) dichalcogenides have been synthesized by reacting 4, 6-dimethyl-2-chloropyrimidine with the corresponding dichalcogenide (E22− where E= S, Se, Te) ion. The unsymmetrical 4, 6-dimethyl-2- (arylchalcogenyl) pyrimidines have also been prepared by reacting 4, 6-dimethyl-2- chloropyrimidine with the arylselenide ion, ArSe−(Ar= phenyl, naphthyl, p-tolyl, 4-chloro-2- ...