The Journal of Organic Chemistry

Taxane Synthesis through Intramolecular Pinacol Coupling at C-1-C-2. Highly Oxygenated C-Aromatic Taxanes

CS Swindell, W Fan

Index: Swindell, Charles S.; Fan, Weiming Journal of Organic Chemistry, 1996 , vol. 61, # 3 p. 1109 - 1118

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Citation Number: 34

Abstract

Chiral, nonracemic intramolecular pinacol coupling substrates 3/20 and 30 have been prepared from ethyl isopropyl ketone and acryloyl chloride, which provide the A-ring and either o-iodobenzyl alcohol or 2, 4-dimethoxybenzyl alcohol, which provide the respective