Synthesis, Characterization, and Reversible Oxygenation of. mu.-Alkoxo Diiron (II) Complexes with the Dinucleating Ligand N, N, N', N'-Tetrakis {(6-methyl-2-pyridyl) …

Y Hayashi, T Kayatani, H Sugimoto…

Index: Hayashi, Yoshihito; Kayatani, Takayuki; Sugimoto, Hideki; Suzuki, Masatatsu; Inomata, Katsuhiko; Uehara, Akira; Mizutani, Yasuhisa; Kitagawa, Teizo; Maeda, Yonezo Journal of the American Chemical Society, 1995 , vol. 117, # 45 p. 11220 - 11229

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Citation Number: 96

Abstract

Abstract: Two new types of dinucleating ligands, symmetric Me4-tpdp and asymmetric Mertpdp, were synthesized (Me4-tpdp= N, N, N', N'-tetrakis {(6-methyl-2-pyridy1) methyl)-1, 3- diaminopropan-2-olate and Me2-tpdp= N, N-bis-{(6-methyl-2-pyridyl) methyl)-hr, AT-bis (2- pyridylmethyl)-l, 3-diaminopropan-2-olate). Their p-alkoxo diiron (I1) complexes [Fe2 (Me4- tpdp)(CsHsCoo)(H2O) l (BF4) 2 (l),[Fe2 (Me4-tpdp)(CF3CO2)(H20) 21 (BF4) 2~ H20 (2), ...