Rhodium thiolate hydroformylation complexes tethered to delamellated γ-zirconium phosphate

S Rojas, S Murcia-Mascarós, P Terreros…

Index: Rojas; Murcia-Mascaros; Terreros; Garcia Fierro New Journal of Chemistry, 2001 , vol. 25, # 11 p. 1430 - 1437

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Citation Number: 8

Abstract

Rhodium thiolate complexes intercalated in crystalline γ-zirconium phosphate or tethered to SiO2-modified γ-zirconium phosphate have been synthesised. It was observed that the addition of a solution of organic silicates to a colloidal suspension of γ-zirconium phosphate yielded amorphous substrates, which displayed very high specific areas (160–650 m2 g− 1). Incorporation of a mercaptocarbonyl rhodium complex resulted in a highly selective and ...