New 7??phosphanorbornenes derived from 2??methyl??1??phenyl??and 1??cyclohexyl??3??methyl??2, 5??dihydro??1H??phosphole 1??oxides

J Kovacs, NB Szabó, Z Nagy, K Ludanyi…

Index: Kovacs, Janos; Szabo, Nora Balazsdi; Nagy, Zoltan; Ludanyi, Krisztina; Keglevich, Gyoergy Heteroatom Chemistry, 2005 , vol. 16, # 5 p. 320 - 326

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Citation Number: 17

Abstract

Abstract Novel 7-phosphanorbornene derivatives, such as 4, 5, 10, and 11 were synthesized utilizing 1-phenyl-2-methyl-2, 5-dihydro-1H-phosphole oxide (1) and 1-cyclohexyl-3-methyl- 2, 5-dihydro-1H-phosphole oxide (7) as the starting materials. Products 4 and 10 were prepared by trapping the corresponding phosphole oxide intermediates (3 and 9, respectively) by N-phenylmaleimide, while 5 and 11 were obtained by the dimerization of ...