The relaxation properties of the excited states of some trans-1, 2-diarylethene analogues (where one aryl group is a methylpyridinium or dimethylimidazolinium group and the other one is a π-excessive furyl or pyrrolyl group) and two all-trans-distyrylbenzene analogues (where the central ring is a methylpyridinium group and the side rings are furyl or methylpyrrolyl groups) have been investigated in buffered (pH 7) aqueous solutions. The ...