Journal of organometallic chemistry

The synthesis and catalytic activity of poly (bis (imino) pyridyl) iron (II) metallodendrimer

ZJ Zheng, J Chen, YS Li

Index: Zheng, Zhan-Jiang; Chen, Jie; Li, Yue-Sheng Journal of Organometallic Chemistry, 2004 , vol. 689, # 19 p. 3040 - 3045

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Citation Number: 38

Abstract

The first and second generation carbosilane dendrimers with silicon hydride terminated were synthesized, and then reacted with bis (imino) pyridyl containing allyl [4-CH2CHCH2- 2, 6-iPr2C6H3NCMe (C5H3N) MeCN (2, 6-iPr2C6H3)], in the presence of H2PtCl6 as a hydrosilylation catalyst, to afford the first and second generation carbosilane supported ligands. Complexation reactions with FeCl2· 4H2O give rise to iron-containing carbosilane ...