Cleavage Reactions of Tetraaryltin with Diphenyl and Alkylene Dithiophosphoric Acids

AAS Elkhaldy, RK Mehrotra…

Index: Elkhaldy, A. A. S.; Mehrotra, R. K.; Srivastava, G. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1992 , vol. 22, p. 997 - 1014

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Citation Number: 5

Abstract

Abstract and Ar4-nSn [S2P (OPh) 2] n (Ar= C6H5, C6H4CH3-p, and n= 1, 2) obtained by the cleavage reaction of tetraaryltin with the corresponding dithiophosphoric acids in molar ratios of 1: 1 and 1: 2 are white microcrystalline, hydrolytically stable solids which are soluble in common organic solvents. Attempts to remove more than two aryl groups were unsuccessful. These compounds have been characterized by molecular weights, IR and ...