Conversion of alkenes to 1, 2-diazides and 1, 2-diamines

WE Fristad, TA Brandvold, JR Peterson…

Index: Fristad, William E.; Brandvold, Timothy A.; Peterson, John R.; Thomson, Scott R. Journal of Organic Chemistry, 1985 , vol. 50, # 19 p. 3647 - 3649

Full Text: HTML

Citation Number: 78

Abstract

RCH= CH2+ 2Mn (III)+ 2N3-+ RC (N3) HCH, N3+ 2Mn (II)(1) nese (II1) method of vicinal difunctionalization is similar to a method of alkene chlorination reported previously by us2 and represents one of the very few methods of introducing vicinal diazide functionality. Previously, Fe (III) 3 and Pb (IV) 4a have been used to convert alkenes to 1, 2-(1)(a) Lando Summer Undergraduate Fellow, 1984.(b) 3M Co. and