Novel azido-phenylselenenylation of double bonds. Evidence for a free-radical process

…, D Chianelli, R Balducci, A Temperini

Index: Tingoli, Marco; Tiecco, Marcello; Chianelli, Donatella; Balducci, Roberta; Temperini, Andrea Journal of Organic Chemistry, 1991 , vol. 56, # 24 p. 6809 - 6813

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Citation Number: 98

Abstract

2RCH (SePh) CHRN3+ PhI+ 2NaOAc spectra. In the case of styrene the other regioisomer 11 could be obtained from the reaction of diphenyl diselenide, sodium azide, and m- nitrobenzenesulfonyl peroxide in a~ etonitrile.~ Reduction of 1 and 11 with LiAlH, in THF afforded the amino derivatives 12 and 13, respectively. The NMR data of compounds 1 and 11, as well as those of 12 and 13 (see Experimental Section), were in agreement with the ...