Poly (9, 9′-spirobifluorene-manganese porphyrin): a new catalytic material for oxidation of alkenes by iodobenzene diacetate and iodosylbenzene

…, P le Maux, J Raul-Berthelot, G Simonneaux

Index: Poriel, Cyril; Ferrand, Yann; Le Maux, Paul; Raul-Berthelot, Joelle; Simonneaux, Gerard Chemical Communications, 2003 , # 9 p. 1104 - 1105

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Citation Number: 19

Abstract

Anodic oxidation of tetraspirobifluorene-manganese porphyrin lead to the coating of the working electrode by insoluble electroactive poly (9, 9′-spirobifluorene-manganese porphyrin) films for which electrochemical behaviour and physicochemical properties are described; these polymeric materials are able to catalyze the heterogeneous epoxidation of styrene with iodobenzene diacetate and iodosylbenzene.