Tetrahedron Letters

Palladium-catalyzed reactions of trialkylstannyl phenyl sulfides with alkenyl bromides. A new diastereoselective synthesis of (E)-1-alkenyl phenyl sulfides

A Carpita, R Rossi, B Scamuzzi

Index: Carpita, Adriano; Rossi, Renzo; Scamuzzi, Barbara Tetrahedron Letters, 1989 , vol. 30, # 20 p. 2699 - 2702

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Citation Number: 64

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... The reaction of easily available stereoisomeric mixtures of 1-alkenyl bromides with molar excesses of trialkylstannyl phenyl sulfides takes place readily in the presence of Pd(PPH 3 ) 4 to afford diastereoselectively (E)-1-alkenyl phenyl sulfides in excellent yields.