Organometallics

Preparation and crystal structures of iron complexes syn-[(. mu.-SPh) Fe (CO) 3] 2,(C5H4SPh) 2Fe,(C5H5) Fe (C5H4SPh), and (C5H4SPh) Fe (C5H4PPh2)

JA Adeleke, YW Chen, LK Liu

Index: Adeleke, J. Adebanjo; Chen, Yu-Wang; Liu, Ling-Kang Organometallics, 1992 , vol. 11, p. 2543 - 2550

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Citation Number: 34

Abstract

The chemistry of (CsH4PPH2) 2Fe, dppf, upon its complexation with transition metals has attracted much interest for use in homogeneous catalysis' and as a possible antitumor agent? As a neighboring atom to P, S usually displays different chemistry from that of P due to a larger electronegativity and ader atomic Size for S. Brubaker reported the preparation and reactivity of a series offerrocenyl sulfide derivatives as bidentate chelating ligand^.^ ...