Organic letters

Distinct Chemoselectivities in the Platinum-Catalyzed 1, 2-Carboalkoxylations of 5-Alkoxypent-1-yn-3-ol Derivatives

CM Ting, CD Wang, R Chaudhuri, RS Liu

Index: Organic Letters, , vol. 13, # 7 p. 1702 - 1705

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Citation Number: 22

Abstract

... Volume: Page: ... Organic Letters. ... alcohol, but its platinum-catalyzed reaction in CH 2 Cl 2 (25 °C, 10 min) gave a 67% yield of five-membered oxacycle 8a (Scheme 2). We obtained also its methoxy derivative 9a that resembled 8a in both (1)H and 13 C NMR ...