The Journal of Organic Chemistry

Oxidative transformations of minor components of nucleic acids. An anomalous reaction course of oxidation of N6, N6-dialkyladenosines and related compounds with …

T Endo, J Zemlicka

Index: Endo, Takeshi; Zemlicka, Jiri Journal of Organic Chemistry, 1988 , vol. 53, # 9 p. 1887 - 1894

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Citation Number: 3

Abstract

Oxidation of Ne-methyladenosine (la) or the corresponding tribenzoate lb with m- chloroperoxybenzoic acid gave AT'-oxides 2a and 2b whereas Ne@-dimethyladenosine tribenzoate (3a) afforded 2', 3', 5'-tri-O-benzoylinosine (4a) and p-methyl-p-formyl derivative 5. The Ne@-diethyladenosine 3b and piperidine derivative 3c yielded only 4a, but MP- dibenzyl compound 3d was not oxidized. Nfl-Dimethyl-2, 4-dinitroaniline(6a) was oxidized ...