Photolyses of organocobaloximes having aralkyl and (alkylthio) carbonyl groups on the. beta.-position. A radical reaction involving the thioester group

M Tada, T Nakamura, M Matsumoto

Index: Tada, Masaru; Nakamura, Tatsuya; Matsumoto, Mitsuhiro Journal of the American Chemical Society, 1988 , vol. 110, # 14 p. 4647 - 4652

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Citation Number: 30

Abstract

Results [2-[(Alkylthio) carbonyl]-4-mesityl-2-methylbutyl] cobaloxime (l),[2-[(alkylthio) carbonyl]-2-(ethoxycarbonyl)-5-phenyl-pentyl] cobaloxime (2), and [2-[(alkylthio) carbonyl]-2- (ethoxy-carbonyl)-4-mesitylbutyl] cobaloxime (3) were prepared from cobaloxime (1) anion (Figure 1) and the corresponding bromides, which were prepared by methylation or ethoxycarbonylation followed by bromomethylation of the corresponding S-alkyl 4-or ...