Synthesis, structure and magnetic properties of oligometallic systems derived from di-and trinuclear copper (II) amido-oximate complexes

SV Kolotilov, D Schollmeyer, LK Thompson…

Index: Kolotilov, Sergey V.; Schollmeyer, Dieter; Thompson, Laurence K.; Golub, Vladimir; Addison, Anthony W.; Pavlishchuk, Vitaly V. Dalton Transactions, 2008 , # 22 p. 3007 - 3014

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Citation Number: 7

Abstract

Three heterometallic complexes [M (H2O) n][Cu3L2 (H2O)](M= Mn2+, Co2+ or Ba2+) and one dinuclear compound (CuDien)(CuL {H2O}) were prepared by interaction of anionic compounds Cu3L22− or CuL2− with the corresponding cations (H4L= 1, 9-dicyano-1, 9-bis (hydroximino)-3, 7-diazanonane-2, 8-dione; Dien= 1, 5-diamino-3-azapentane). The complexes [M (H2O) n][Cu3L2 (H2O)] have a polymeric structure, formed via ...