Highly stabilized copper (III) complexes

…, TJ Collins, TG Richmond, BD Santarsiero…

Index: Anson, Fred C.; Collins, Terrence J.; Richmond, Thomas G.; Santarsiero, Bernard D.; Toth, James E.; Treco, Brian G. R. T. Journal of the American Chemical Society, 1987 , vol. 109, # 10 p. 2974 - 2979

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Citation Number: 84

Abstract

Abstract: It has been possible to synthesize a family of copper complexes in the rare+ I11 oxidation state by employing strongly donating polyanionic chelating (PAC) ligands containing organic N-amido and oxido donors. The X-ray crystal structure of one example,[PPh4][Cu (q4-4)]. 2H20 (H44= 1, 2-bis (2-hydroxy-2-methylpropanarnido) benzene), is reported. The metal center is found in a square-planar environment with ...