Journal of organometallic chemistry

Reactivite du derive lithie issu du dioxolanne du levulate de trimethylsilyle vis-a-vis des derives carbonyles: Une methode directe d'olefination des aldehydes …

JL Moreau, R Couffignal

Index: Moreau, Jean-Louis; Couffignal, Rene Journal of Organometallic Chemistry, 1985 , vol. 297, p. 1 - 12

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Citation Number: 3

Abstract

Abstract At− 60 C and in ether, the organolitium reagent produced by trimethylsilyl 4, 4- ethylenedioxypentanoate reacts with aldehydes and ketones, and gives the expected β- hydroxyacids. The β-ethylenic ketones are isolated when the condensation is carried out with aromatic aldehydes and ketones. This proves to be an efficient route for carbonyl olefination.