4-(Pyridin-2-yl) thiazol-2-yl thioglycosides as bidentate ligands for oligosaccharide synthesis via temporary deactivation

P Pornsuriyasak, NP Rath…

Index: Pornsuriyasak, Papapida; Rath, Nigam P.; Demchenko, Alexei V. Chemical Communications, 2008 , # 43 p. 5633 - 5635

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Citation Number: 7

Abstract

Traditional linear approaches for oligosaccharide assembly are cumbersome, and consequently the availability of complex glycostructures remains insufficient to address the challenges of modern glycosciences. 1–4 Recent improvements for oligosaccharide synthesis, ie selective activation of one leaving group over another 5–9 or chemoselective activation of building blocks wherein reactivity is dictated by the nature of protecting groups, 10–13 significantly shorten ...