Calorimetric determination of thermodynamic parameters for the dissociations of acids in dipolar aprotic solvents.

…, T Nakamura, K Takizawa, A Takeda

Index: Izutsu, Kosuke; Nakamura, Toshio; Takizawa, Katsumi; Takeda, Akihiko Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 2 p. 455 - 458

Full Text: HTML

Citation Number: 5

Abstract

A calorimetric method has been investigated for the determination of the thermodynamic parameters of acid dissociations in dipolar aprotic solvents. For the dissociations of monoprotonated bases BH+(B: aniline, pyridine, triethylamine, tributylamine, triethanolamine, 1, 3-diphenylguanidine and 1, 1, 3, 3-tetramethylguanidine) in N, N- dimethylformamide, dimethyl sulfoxide (DMSO), acetonitrile and propylene carbonate, the ...