New iodo-and nitro-substituted pyrroles

…, OV Kharitonova, AG Efimkin, TA Solomentseva

Index: Mironov; Kharitonova; Efimkin; Solomentseva Russian Journal of Organic Chemistry, 2005 , vol. 41, # 11 p. 1654 - 1656

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Citation Number: 3

Abstract

Abstract Treating 2, 5-dimethyl-4-ethoxycarbonyl-and 2, 5-dimethyl-4-carboxypyrroles with iodine furnished 3-iodo-2, 5-dimethyl-4-ethoxycarbonyl-and 3, 4-diiodo-2, 5- dimethylpyrroles. It was established that 3-iodo-2, 5dimethyl-4-ethoxycarbonylpyrrole reacted at heating with silver nitrite to afford 2, 5-dimethyl-3-nitro-4-ethoxycarbonylpyrrole, and the same reagent oxidized 3, 4-diiodo-2, 5-dimethylpyrrole to give 3, 4-diiodo-2- ...