Abstract Treating 2, 5-dimethyl-4-ethoxycarbonyl-and 2, 5-dimethyl-4-carboxypyrroles with iodine furnished 3-iodo-2, 5-dimethyl-4-ethoxycarbonyl-and 3, 4-diiodo-2, 5- dimethylpyrroles. It was established that 3-iodo-2, 5dimethyl-4-ethoxycarbonylpyrrole reacted at heating with silver nitrite to afford 2, 5-dimethyl-3-nitro-4-ethoxycarbonylpyrrole, and the same reagent oxidized 3, 4-diiodo-2, 5-dimethylpyrrole to give 3, 4-diiodo-2- ...