Dalton Transactions

A spectroscopic study on the coordination and solution structures of the interaction systems between biperoxidovanadate complexes and the pyrazolylpyridine-like …

XY Yu, L Deng, B Zheng, BR Zeng, P Yi, X Xu

Index: Yu, Xian-Yong; Deng, Lin; Zheng, Baishu; Zeng, Bi-Rong; Yi, Pinggui; Xu, Xin Dalton Transactions, 2014 , vol. 43, # 4 p. 1524 - 1533

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Citation Number: 5

Abstract

In order to understand the substitution effects of pyrazolylpyridine (pzpy) on the coordination reaction equilibria, the interactions between a series of pzpy-like ligands and biperoxidovanadate ([OV (O 2) 2 (D 2 O)]−/[OV (O 2) 2 (HOD)]−, abbrv. bpV) have been explored using a combination of multinuclear (1 H, 13 C, and 51 V) magnetic resonance, heteronuclear single quantum coherence (HSQC), and variable temperature NMR in a ...