e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

Copper-mediated fluorination of arylboronate esters. Identification of a Copper (III) Fluoride Complex

PS Fier, J Luo, JF Hartwig

Index: Journal of the American Chemical Society, , vol. 135, # 7 p. 2552 - 2559

Full Text: HTML

Citation Number: 82

Abstract

... Journal ... Department of Chemistry, University of Victoria, PO Box 3065, Victoria, British Columbia V8W 3V6, Canada. J. Am. Chem. ... 2013, 135 (7), pp 2552–2559. DOI: 10.1021/ja310909q. Publication Date (Web): February 5, 2013. Copyright © 2013 American Chemical Society. ...

Pinacol Structure

[4-(Dimethylcarbamoyl)phenyl]boronic acid Structure

[4-(Dimethylcar...

~%

4-(N,N-Dimethylaminocarbonyl)phenylboronic acid, pinacol ester Structure

4-(N,N-Dimethyl...

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Pinacol Structure

4-Trifluoromethylphenylboronic acid Structure

4-Trifluorometh...

~%

4,4,5,5-TETRAMETHYL-2-(4-(TRIFLUOROMETHYL)PHENYL)-1,3,2-DIOXABOROLANE Structure

4,4,5,5-TETRAME...

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Pinacol Structure

4-Biphenylboronic acid Structure

4-Biphenylboron...

~%

4-biphenylboronic acid, pinacol ester Structure

4-biphenylboron...

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4-Butylphenylboronic acid pinacol ester Structure

4-Butylphenylbo...

~11%

Butylbenzene Structure

1-butyl-4-fluoro-benzene Structure

1-butyl-4-fluor...

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tolylboronic acid Structure

tolylboronic acid

~%

2-Fluorotoluene Structure

2-Fluorotoluene

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p-Iodobenzeneboronic acid Structure

p-Iodobenzenebo...

~%

4-Fluoroiodobenzene Structure

4-Fluoroiodobenzene

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Pinacol Structure

3-Methoxycarbonylphenylboronic acid Structure

3-Methoxycarbon...

~%

3-Methoxycarbonylphenylboronic acid pinacol ester Structure

3-Methoxycarbon...

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Pinacol Structure

1-(tert-butoxycarbonyl)-1H-indole-5-boronic acid Structure

1-(tert-butoxyc...

~%

tert-butyl 5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole-1-carboxylate Structure

tert-butyl 5-(4...

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Potassium 4-butylphenyltrifluoroborate Structure

Potassium 4-but...

~37%

Butylbenzene Structure

1-butyl-4-fluoro-benzene Structure

1-butyl-4-fluor...

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N/A Structure

~23%

Butylbenzene Structure

1-butyl-4-fluoro-benzene Structure

1-butyl-4-fluor...

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2-(4-butylphenyl)-5,5-dimethyl-1,3,2-dioxaborinane Structure

2-(4-butylpheny...

~14%

Butylbenzene Structure

1-butyl-4-fluoro-benzene Structure

1-butyl-4-fluor...

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(4-Butylphenyl)boronic acid Structure

(4-Butylphenyl)...

~%

Butylbenzene Structure

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(4-Butylphenyl)boronic acid Structure

(4-Butylphenyl)...

~%

Butylbenzene Structure

1-butyl-4-fluoro-benzene Structure

1-butyl-4-fluor...

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Pinacol Structure

(3-Cyanophenyl)boronic acid Structure

(3-Cyanophenyl)...

~%

3-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile Structure

3-(4,4,5,5-Tetr...

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Steric and chelate directing effects in aromatic borylation

[Journal of the American Chemical Society, , vol. 122, # 51 p. 12868 - 12869]