The Journal of Organic Chemistry

Synthesis of 3-substituted 1, 4-pentadiyn-3-ols

RD Dillard, DE Pavey

Index: Dillard,R.D.; Pavey,D.E. Journal of Organic Chemistry, 1971 , vol. 36, # 6 p. 749 - 752

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Citation Number: 6

Abstract

Reports in the literature on the preparation of tertiary ethynyl carbinols have been numerous, and a wide variety of reatgents and reaction conditions have been described. For compounds having an unsubstituted terminal acetylenic group, the most familiar method has involved the use of a metal acetylide in liquid ammonia.'t These include monoethynyl carbinols with various alkyl or aryl substituents on the a carbon. x"