Tetrahedron letters

Potassium triisopropylsilanethiolate: vinyl and aryl sulfides through Pd-catalyzed cross coupling

AM Rane, EI Miranda, JA Soderquist

Index: Rane, Anil M.; Miranda, Edgar I.; Soderquist, John A. Tetrahedron Letters, 1994 , vol. 35, # 20 p. 3225 - 3226

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Citation Number: 46

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Vinyl and aryl halides are efficiently converted, under Pd catalysis, with KSTIPS (1) to the corresponding silyl sulfides (2, 3). The naphthyl derivative was easily hydrolyzed to the mercaptan 4, or alkylated or alkenylated to provide unsymmetrical sulfides (5, 6). ... Compound 1 efficiently ...