Chemistry of nitrosoimines. XV. Reactions of 3-substituted 2-nitrosoimino-2, 3-dihydrobenzothiazoles with lithium aluminum hydride and diazo compounds.

K Akiba, T Kawamura, M Ochiumi…

Index: Akiba,K. et al. Bulletin of the Chemical Society of Japan, 1976 , vol. 49, # 7 p. 1913 - 1916

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Citation Number: 9

Abstract

3-Substituted 2-nitrosoimino-2, 3-dihydrobenzothiazoles (1) were reduced with lithium aluminum hydride to give the corresponding thiazolone azines and bis [o-(N-substituted N- formylamino) phenyl] disulfides as major products. Reactions of 1 with some substituted diazomethanes gave the corresponding unsymmetrical azine N-monoxides (16) or azines (17) depending on the structure of the diazomethane.

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