Nitrogen-containing derivatives of pyrone-4-carboxylic acid

…, SM Klyuev, YV Burov, VN Zhukov, AE Vasil'ev

Index: Khutornenko, G. A.; Klyuev, S. M.; Burov, Yu. V.; Zhukov, V. N.; Vasil'ev, A. E. Pharmaceutical Chemistry Journal, 1983 , vol. 17, # 4 p. 261 - 265 Khimiko-Farmatsevticheskii Zhurnal, 1983 , vol. 17, # 4 p. 420 - 423

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Abstract

Compounds IIa-e give a blue color with iron chloride, in contrast to the acid I which gives a red color, and this enables the course of the reaction to be followed. Compounds IIa-e are amino acids and form salts with alkalis; the hydrochlorides are easily decomposed because the amino group is weakly basic: From dilute acid solutions of salts only the free bases can be obtained. An exception is the diaminocarboxylic acid betaine IIe which has a ...