Tetrahedron

Efficient Heck cross-coupling of 3-iodo-benzopyrones with olefins under microwave irradiation without phosphine

Y Zhang, Z Lv, H Zhong, M Zhang, T Zhang, W Zhang…

Index: Zhang, Yikai; Lv, Zhiliang; Zhong, Hanyu; Zhang, Mingfeng; Zhang, Tao; Zhang, Wannian; Li, Ke Tetrahedron, 2012 , vol. 68, # 47 p. 9777 - 9787

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Citation Number: 6

Abstract

An efficient and effective microwave-assisted Heck cross-coupling of different terminal olefins with various 3-iodo-benzopyrones including sterically hindered, electron-rich, electron-neutral, and electron-deficient is developed. It proceeded faster and generally gave good to excellent yields under microwave irradiation, phosphine-free, and air condition. The reaction could render this method particularly attractive for the efficient preparation of ...