The Journal of Organic Chemistry

Conjugate Electrophilic Iodofluorination of Fluoroolefins

VA Petrov, CG Krespan

Index: Petrov, Viacheslav A.; Krespan, Carl G. Journal of Organic Chemistry, 1996 , vol. 61, # 26 p. 9605 - 9607

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Citation Number: 17

Abstract

Many such reactions are known and are summarized in several reviews. 1-3 In the addition of halogen fluoride across a hydrocarbon double bond, a typical reagent combination includes an N-halogen compound (N-halosuccinimides or hexachloromelamine) and anhydrous HF (AHF) or another source of HF, such as the complex HF/pyridine. 4, 5 Addition of halogen fluorides across the electron poor double bond of fluoroolefins is generally ...