N-heterocyclic carbene adducts of cyclopalladated ferrocenylpyridine containing chloride or iodide anions: synthesis, crystal structures and application in the coupling …

HM Li, C Xu, LM Duan, XH Lou, ZQ Wang, Z Li…

Index: Li, Hong-Mei; Xu, Chen; Duan, Lu-Meng; Lou, Xin-Hua; Wang, Zhi-Qiang; Li, Zhen; Fan, Yao-Ting Transition Metal Chemistry, 2013 , vol. 38, # 3 p. 313 - 318

Full Text: HTML

Citation Number: 6

Abstract

Abstract Two air-stable N-heterocyclic carbene (NHC) adducts of cyclopalladated ferrocenylpyridine containing chloride or iodide anions 2–3 have been easily prepared from the bridge-splitting reaction of the palladacyclic dimer 1 and anion exchange reaction, respectively. They were characterized by elemental analysis, IR, 1 H, and 13 C NMR. Additionally, the structures of these complexes were determined by single-crystal X-ray ...