Copper-catalyzed cross-coupling and carbonylative cross-coupling of organostannanes and organoboranes with hypervalent iodine compounds

SK Kang, T Yamaguchi, TH Kim…

Index: Kang, Suk-Ku; Yamaguchi, Tokutaro; Kim, Tae-Hyun; Ho, Pil-Su Journal of Organic Chemistry, 1996 , vol. 61, # 26 p. 9082 - 9083

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Citation Number: 113

Abstract

The palladium-catalyzed cross-coupling of organostannanes and organoboranes with an organic electrophile (ie, halides and triflates) are known as the Stille and Suzuki reactions, 1, 2 respectively, and have become extremely powerful tools for the construction of carboncarbon bonds. Although these coupling reactions tolerate many functional groups, they usually require a longer reaction time and higher temperatures, which reduce the ...