Homolytic reactions of N-bromohexamethyldisilazane with trialkyl (phenylalkoxy) derivatives of silicon and tin

…, TA Podgorbunskaya, MG Voronkov

Index: Rakhlin; Podgorbunskaya; Voronkov Russian Journal of General Chemistry, 2010 , vol. 80, # 5 p. 930 - 935

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Abstract

Abstract The main product of the photoinduced reaction of N-bromohexamethyldisilazane with trialkyl-(benzyloxy) derivatives of silicon and tin R 3 MO (CH 2) n Ph (R= Me, Et; M= Si, Sn; n= 1) is N, N-dibenzylidene-C-phenylmethanediamine (hydrobenzamide). For M= Si, with increase of the length of the methylene chain between the oxygen atom and the phenyl group (n= 2, 3), the similar reaction affords the product of bromination of the benzylic ...