Three-Component Coupling of Acylphosphonates and Two Carbonyl Compounds Promoted by Low-Valent Samariums: One-Pot Synthesis of β- …

…, Y Itono, A Nagafuji, Y Naito, T Shishido…

Index: Takaki, Ken; Itono, Yuichiro; Nagafuji, Akihiro; Naito, Yoji; Shishido, Tetsuya; Takehira, Katsuomi; Makioka, Yoshikazu; Taniguchi, Yuki; Fujiwara, Yuzo Journal of Organic Chemistry, 2000 , vol. 65, # 2 p. 475 - 481

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Citation Number: 22

Abstract

Three-component coupling of acylphosphonates and two carbonyl compounds leading to β- hydroxyphosphonates has been achieved with low-valent samariums. Thus, acylphosphonates reacted with aldehydes in the presence of semicatalytic amounts of ...

~28%

~71%

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