Helvetica Chimica Acta

Norbornanes. Part 10. Solvolysis of the Stereoisomeric 6??Cyano??2??norbornyl p??Toluenesulfonates. A Correction

CA Grob, D Herzfeld

Index: Grob, Cyril A.; Herzfeld, Danielle Helvetica Chimica Acta, 1982 , vol. 65, # 8 p. 2443 - 2447

Full Text: HTML

Citation Number: 4

Abstract

Abstract The solvolysis products of the stereoisomeric 6-cyano-2-norbornyl p-toluene sulfonates 1-4 (R [DOUBLE BOND] CN) in dioxane/water 7: 3 have been determined. In contrast to an earlier report the 6exo-cyano-2exo-norbornyl p-toluenesulfonate (1; R [DOUBLE BOND] CN) yields 30% of the 2endo-alcohol 9 (R [DOUBLE BOND] CN) beside the 2exo-alcohol 10 and the norbornenes 12 and 13. The results confirm that-I ...