e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521
Tetrahedron letters
Deuterium kinetic isotope effects in homogeneous decatungstate catalyzed photooxygenation of 1, 1-diphenylethane and 9-methyl-9H-fluorene: evidence for a …
IN Lykakis, M Orfanopoulos
Index: Lykakis, Ioannis N.; Orfanopoulos, Michael Tetrahedron Letters, 2005 , vol. 46, # 45 p. 7835 - 7839
The homogeneous decatungstate W10O324-catalyzed photooxygenation of 1, 1- diphenylethane and 9-methyl-9H-fluorene has been studied mechanistically. The primary and β-secondary kinetic isotope effects provide strong evidence for a stepwise mechanism, with a hydrogen atom abstraction in the rate-determining step.
