Formation of Secondary or Tertiary Aliphatic Amines in Aqueous Media

A Marieta Simion, T Arimura, A Miyazawa…

Index: Marieta Simion, Alina; Arimura, Takashi; Miyazawa, Akira; Simion, Cristian; Surya Prakash; Olah, George A.; Tashiro, Masashi Synthetic Communications, 2009 , vol. 39, # 16 p. 2859 - 2865

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Abstract

Abstract Secondary and tertiary amines can be easily obtained from primary and secondary amines, respectively, in completely aqueous media, in the presence of a bicatalytic system formed of cheap commercial aluminum (Al) powder and 5% rhodium (Rh) or ruthenium (Ru) deposed on charcoal.

~80%

~14%

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