Tetrahedron letters

6-Trifluoromethanesulfonyloxy-4 (3H)-pyrimidinones as versatile intermediates for the synthesis of 6-functionalized 4 (3H)-pyrimidinones

EC Taylor, P Zhou, CM Tice

Index: Taylor, Edward C.; Zhou, Ping; Tice, Colin M. Tetrahedron Letters, 1997 , vol. 38, # 25 p. 4343 - 4346

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Citation Number: 18

Abstract

The reaction of 6-trifluoromethanesulfonyloxy-4 (3H)-pyrimidinones with Me2Cu (CN) Li2, and with vinyl tributyltin, trimethylsilylacetylene, and zinc cyanide with palladium catalysis, are described for the synthesis of a variety of fully functionalized 6-substituted-4 (3H)- pyrimidinones of interest as herbicides.