Synthesis, structure, and conformational mobility of a vaulted trans-bis (o-aminophenolato) platinum (II) complex

N Komiya, K Takahashi, T Tanaka, A Yoshida…

Index: Komiya, Naruyoshi; Takahashi, Koichi; Tanaka, Tomoya; Yoshida, Atsushi; Naota, Takeshi Transition Metal Chemistry, 2013 , vol. 38, # 6 p. 659 - 664

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Citation Number: 4

Abstract

Abstract The synthesis, structure, and conformational mobility of a trans-bis (aminophenolato) platinum (II) complex bearing a dodecamethylene bridge,[Pt (L)](1)[H 2 L= N, N′-Dimethyl-N, N′-bis (2-hydroxyphenylmethyl) dodecane-1, 12-diamine] are described. The 2D NMR and X-ray diffraction analysis revealed that the complex has a “reversed U”-shaped syn conformation in the solution state, which is mainly due to steric ...