Journal of the American Chemical Society

The condensation of carboxylic acid hydrazides with carbon disulfide

C Ainsworth

Index: Ainsworth Journal of the American Chemical Society, 1956 , vol. 78, p. 4475,4476

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Citation Number: 57

Abstract

The reaction of carboxylic acid hydrazides, carbon disulfide and alcoholic alkali to form 2- substituted-A2-1, 3, 4-oxadiazo-line-5-thiones has been found to be general for aliphatic, aromatic and heterocyclic carboxylic acid hydrazides and dihydrazides. An interesting thermal isomerization of 2-(3-(5)-pyrazolyl)-A2-l, 3, 1-oxadiazoline-5-thione(i'111) to 7- mercaptopyrazolo [1, 5-d] as-triazin-4 (5H)-one (X) was observed.