e.g. Filippa Pettersson or Cancer Res. 75(6) , 1102-12, (2015) or 10.1002/anie.201600521

One-Pot Synthesis of Diarylmethanones through Palladium-Catalyzed Sequential Coupling and Aerobic Oxidation of Aryl Bromides with Acetophenone as a Latent …

X Wang, FD Liu, HY Tu, AD Zhang

Index: Jereb, Marjan; Vrazic, Dejan Organic and Biomolecular Chemistry, 2013 , vol. 11, # 12 p. 1978 - 1999

Full Text: HTML

Citation Number: 7

Abstract

... of Pesticide & Chemical Biology of Ministry of Education, College of Chemistry, Central China ... DOI: 10.1021/jo5010185. Publication Date (Web): June 27, 2014. Copyright © 2014 American Chemical Society. ... is found not only in natural products(1) but also in organic materials,(2 ...

Methylbenzylalcohol Structure

Methylbenzylalcohol

~%

Triphenylmethane Structure

Triphenylmethane

Acetophenone Structure

1-(4-Methylphenyl)ethanol Structure

1-(4-Methylphen...

~%

Triphenylmethane Structure

Triphenylmethane

4'-Methylacetophenone Structure

4'-Methylacetop...

N/A Structure

~%

Triphenylmethane Structure

Triphenylmethane

3'-Methoxyacetophenone Structure

3'-Methoxyaceto...

1-(4-Bromophenyl)ethanol Structure

1-(4-Bromopheny...

~%

Triphenylmethane Structure

Triphenylmethane

1-(4-Bromophenyl)ethanone Structure

1-(4-Bromopheny...

Triphenylmethyl Chloride Structure

Triphenylmethyl...

Benzyl alcohol Structure

~%

Triphenylmethane Structure

Triphenylmethane

Benzaldehyde Structure

2-Octanol Structure

Triphenylmethyl Chloride Structure

Triphenylmethyl...

~%

Triphenylmethane Structure

Triphenylmethane

2-Octanone Structure

Triphenylmethyl Chloride Structure

Triphenylmethyl...

Cyclohexanol Structure

~%

Triphenylmethane Structure

Triphenylmethane

Cyclohexanone Structure

alpha-3-dimethylbenzyl alcohol Structure

alpha-3-dimethy...

Triphenylmethyl Chloride Structure

Triphenylmethyl...

~%

Triphenylmethane Structure

Triphenylmethane

3'-Methylacetophenone Structure

3'-Methylacetop...

1-(4-Fluorophenyl)ethanol Structure

1-(4-Fluorophen...

Triphenylmethyl Chloride Structure

Triphenylmethyl...

~%

Triphenylmethane Structure

Triphenylmethane

4'-Fluoroacetophenone Structure

4'-Fluoroacetop...

1-(4-Chlorophenyl)ethanol Structure

1-(4-Chlorophen...

Triphenylmethyl Chloride Structure

Triphenylmethyl...

~%

Triphenylmethane Structure

Triphenylmethane

1-(4-Chlorophenyl)ethanone Structure

1-(4-Chlorophen...

1-(3-nitrophenyl)ethanol Structure

1-(3-nitropheny...

Triphenylmethyl Chloride Structure

Triphenylmethyl...

~%

Triphenylmethane Structure

Triphenylmethane

3'-Nitroacetophenone Structure

3'-Nitroacetophenone

1-(4-nitrophenyl)ethanol Structure

1-(4-nitropheny...

Triphenylmethyl Chloride Structure

Triphenylmethyl...

~%

Triphenylmethane Structure

Triphenylmethane

4-Nitroacetophenone Structure

4-Nitroacetophenone

1-[4-(TrifluoroMethyl)phenyl]ethanol Structure

1-[4-(Trifluoro...

Triphenylmethyl Chloride Structure

Triphenylmethyl...

~%

4'-(Trifluoromethyl)acetophenone Structure

4'-(Trifluorome...

Triphenylmethane Structure

Triphenylmethane

bis[4,4'-dimethoxy(diphenylmethyl)] ether Structure

bis[4,4'-dimeth...

~89%

DMBP Structure

Benzene,1,1'-methylenebis[4-methoxy- Structure

Benzene,1,1'-me...

[bis(p-anisyl)methyl] [bis(m-nitrophenyl)methyl] ether Structure

[bis(p-anisyl)m...

~43%

DMBP Structure

Benzene,1,1'-methylenebis[4-methoxy- Structure

Benzene,1,1'-me...

N/A Structure

bis[bis(p-anisyl)deuteromethyl] ether Structure

bis[bis(p-anisy...

bis[4,4'-dimethoxy(diphenylmethyl)] ether Structure

bis[4,4'-dimeth...

~%

DMBP Structure

Benzene,1,1'-methylenebis[4-methoxy- Structure

Benzene,1,1'-me...

Detail

(4-methoxyphenyl)-(4-methylphenyl)methanol Structure

(4-methoxypheny...

~%

1-methoxy-4-[(4-methylphenyl)methyl]benzene Structure

1-methoxy-4-[(4...

Methanone,(4-methoxyphenyl)(4-methylphenyl)- Structure

Methanone,(4-me...

4-(4-methylbenzyl)-2-((p-anisyl)(p-tolyl)methyl)-1-methoxybenzene Structure

4-(4-methylbenz...

5-[(10,11-dihydro-5H-dibenzo[a,d]cyclohepten-5-yl)oxy]-10,11-dihydro-5H-dibenzo[a,d]cycloheptene Structure

5-[(10,11-dihyd...

~78%

5H-dibenzo[a,d]cycloheptene Structure

5H-dibenzo[a,d]...

Dibenzosuberone Structure

Dibenzosuberone

5-[(5H-dibenzo[a,d]cyclohepten-5-yl)oxy]-5H-dibenzo[a,d]cycloheptene Structure

5-[(5H-dibenzo[...

~75%

5H-dibenzo[a,d]cycloheptene Structure

5H-dibenzo[a,d]...

Dibenzosuberenone Structure

Dibenzosuberenone

[bis(4-methoxy-3,5-dimethylphenyl)]methyl diphenylmethyl ether Structure

[bis(4-methoxy-...

~%

Benzophenone Structure

Bis(diphenylmethyl) ether Structure

Bis(diphenylmet...

3,3',5,5'-Tetramethyl-4,4'-dimethoxydiphenylmethane Structure

3,3',5,5'-Tetra...

Detail

((1-(4-fluorophenyl)ethoxy)methanetriyl)tribenzene Structure

((1-(4-fluoroph...

~81%

Triphenylmethane Structure

Triphenylmethane

4'-Fluoroacetophenone Structure

4'-Fluoroacetop...

bis[(3-bromo-4-methoxyphenyl)(phenyl)methyl] ether Structure

bis[(3-bromo-4-...

~84%

Methanone, (3-bromo-4-methoxyphenyl)phenyl- (en) Structure

Methanone, (3-b...

2-Bromo-1-methoxy-4-(phenylmethyl)benzene Structure

2-Bromo-1-metho...

(3-bromo-4-methoxyphenyl)(phenyl)methanol Structure

(3-bromo-4-meth...

~%

Methanone, (3-bromo-4-methoxyphenyl)phenyl- (en) Structure

Methanone, (3-b...

2-Bromo-1-methoxy-4-(phenylmethyl)benzene Structure

2-Bromo-1-metho...

bis[(4-methoxy-3,5-dimethylphenyl)(p-tolyl)methyl] ether Structure

bis[(4-methoxy-...

~91%

(4-methoxy-3,5-dimethylphenyl)-(4-methylphenyl)methanone Structure

(4-methoxy-3,5-...

2-methoxy-1,3-dimethyl-5-[(4-methylphenyl)methyl]benzene Structure

2-methoxy-1,3-d...

(4-methoxy-3,5-dimethylphenyl)(p-tolyl)methanol Structure

(4-methoxy-3,5-...

~%

(4-methoxy-3,5-dimethylphenyl)-(4-methylphenyl)methanone Structure

(4-methoxy-3,5-...

2-methoxy-1,3-dimethyl-5-[(4-methylphenyl)methyl]benzene Structure

2-methoxy-1,3-d...

1-(4-Fluorophenyl)ethanol Structure

1-(4-Fluorophen...

Triphenylmethyl Chloride Structure

Triphenylmethyl...

~%

Triphenylmethane Structure

Triphenylmethane

4'-Fluoroacetophenone Structure

4'-Fluoroacetop...

Cyclohexyl(triphenylmethyl) ether Structure

Cyclohexyl(trip...

~0%

Triphenylmethane Structure

Triphenylmethane

Cyclohexanone Structure

Ethyl trityl ether Structure

Ethyl trityl ether

~88%

Triphenylmethane Structure

Triphenylmethane

ch3cho Structure

(diphenyl-phenylmethoxy-methyl)benzene Structure

(diphenyl-pheny...

~97%

Triphenylmethane Structure

Triphenylmethane

Benzaldehyde Structure

bis[(p-anisyl)(2,3-dihydrobenzo[1,4]dioxin-6-yl)methyl] ether Structure

bis[(p-anisyl)(...

~78%

(p-anisyl)(2,3-dihydro-benzo[1,4]dioxin-6-yl)methane Structure

(p-anisyl)(2,3-...

2,3-dihydro-1,4-benzodioxin-6-yl-(4-methoxyphenyl)methanone Structure

2,3-dihydro-1,4...

(p-anisyl)(2,3-dihydr-benzo[1,4]dioxin-6-yl)methanol Structure

(p-anisyl)(2,3-...

~%

(p-anisyl)(2,3-dihydro-benzo[1,4]dioxin-6-yl)methane Structure

(p-anisyl)(2,3-...

2,3-dihydro-1,4-benzodioxin-6-yl-(4-methoxyphenyl)methanone Structure

2,3-dihydro-1,4...

bis[(4-methoxy-3,5-dimethylphenyl)(p-tolyl)methyl] ether Structure

bis[(4-methoxy-...

~95%

(4-methoxy-3,5-dimethylphenyl)-(4-methylphenyl)methanone Structure

(4-methoxy-3,5-...

2-methoxy-1,3-dimethyl-5-[(4-methylphenyl)methyl]benzene Structure

2-methoxy-1,3-d...

(4-methoxy-3,5-dimethylphenyl)(p-tolyl)methanol Structure

(4-methoxy-3,5-...

~%

(4-methoxy-3,5-dimethylphenyl)-(4-methylphenyl)methanone Structure

(4-methoxy-3,5-...

2-methoxy-1,3-dimethyl-5-[(4-methylphenyl)methyl]benzene Structure

2-methoxy-1,3-d...

Cyclohexyl(triphenylmethyl) ether Structure

Cyclohexyl(trip...

~93%

Triphenylmethane Structure

Triphenylmethane

Cyclohexanone Structure

Triphenylmethyl (R,S)-sec-phenethyl ether Structure

Triphenylmethyl...

~88%

Triphenylmethane Structure

Triphenylmethane

Acetophenone Structure

((1-(p-tolyl)ethoxy)methanetriyl)tribenzene Structure

((1-(p-tolyl)et...

~83%

Triphenylmethane Structure

Triphenylmethane

4'-Methylacetophenone Structure

4'-Methylacetop...

((1-(m-tolyl)ethoxy)methanetriyl)tribenzene Structure

((1-(m-tolyl)et...

~86%

Triphenylmethane Structure

Triphenylmethane

3'-Methylacetophenone Structure

3'-Methylacetop...

((1-(4-fluorophenyl)ethoxy)methanetriyl)tribenzene Structure

((1-(4-fluoroph...

~92%

Triphenylmethane Structure

Triphenylmethane

4'-Fluoroacetophenone Structure

4'-Fluoroacetop...

((1-(3-methoxyphenyl)ethoxy)methanetriyl)tribenzene Structure

((1-(3-methoxyp...

~84%

Triphenylmethane Structure

Triphenylmethane

3'-Methoxyacetophenone Structure

3'-Methoxyaceto...

((1-(4-chlorophenyl)ethoxy)methanetriyl)tribenzene Structure

((1-(4-chloroph...

~73%

Triphenylmethane Structure

Triphenylmethane

1-(4-Chlorophenyl)ethanone Structure

1-(4-Chlorophen...

N/A Structure

~77%

Triphenylmethane Structure

Triphenylmethane

1-(4-Bromophenyl)ethanone Structure

1-(4-Bromopheny...

((1-(3-nitrophenyl)ethoxy)methanetriyl)tribenzene Structure

((1-(3-nitrophe...

~84%

Triphenylmethane Structure

Triphenylmethane

3'-Nitroacetophenone Structure

3'-Nitroacetophenone

((1-(4-nitrophenyl)ethoxy)methanetriyl)tribenzene Structure

((1-(4-nitrophe...

~79%

Triphenylmethane Structure

Triphenylmethane

4-Nitroacetophenone Structure

4-Nitroacetophenone

Structure

~77%

4'-(Trifluoromethyl)acetophenone Structure

4'-(Trifluorome...

Triphenylmethane Structure

Triphenylmethane

Phase transfer catalyzed desulfurization reactions

[Alper, Howard; Sibtain, Fazle; Heveling, Josef Tetrahedron Letters, 1983 , vol. 24, # 48 p. 5329 - 5332]

Modified molybdenum carbonyl species; excellent reagents for...

[Alper, Howard; Blais, Claude Journal of the Chemical Society, Chemical Communications, 1980 , # 4 p. 169 - 170]

Desulfurization of thiols and thioketones by sodium triethyl...

[Alper, Howard; Ripley, Sharon; Prince, Trish L. Journal of Organic Chemistry, 1983 , vol. 48, # 2 p. 250 - 252]

Synthetic methods and reactions. 112. Synthetic transformati...

[Olah, George A.; Husain, Altaf; Singh, Brij P.; Mehrotra, Ashok K. Journal of Organic Chemistry, 1983 , vol. 48, # 21 p. 3667 - 3672]

On the Di-1-naphthylcarbene-Dibenzofluorene Rearrangement an...

[Regimbald-Krnel, Michele; Wentrup, Curt Journal of Organic Chemistry, 1998 , vol. 63, # 23 p. 8417 - 8423]