Russian Journal of General Chemistry

Micellar catalysis in the systems arylamine-diphenylamine-NO 2−

SY Doronin, RK Chernova

Index: Doronin, S. Yu.; Chernova Russian Journal of General Chemistry, 2008 , vol. 78, # 11 p. 2019 - 2024

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Abstract

Abstract By methods of UV and IR spectroscopy and thermogravimetry reactions of diazotizaion and azo coupling were studied in the systems of primary arylamine (p-nitro-, p- carboxy-and p-sulfoaniline)-diphenylamine-nitrite ion in water and micellar media on the basis of surfactants. The micellar catalysis effect of sodium dodecylsulfate in the micellar media was revealed. Rate of diazotization was shown to be independent of the surfactants ...