Tetrahedron

Arylation of potassium 2, 4-pentanedionate via S RN 1 on diazosulfides

C Dell'Erba, M Novi, G Petrillo, C Tavani, P Bellandi

Index: Dell'Erba; Novi; Petrillo; Tavani; Bellandi Tetrahedron, 1991 , vol. 47, # 2 p. 333 - 342

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Citation Number: 30

Abstract

Download full text in PDF Opens in a new window. Article suggestions will be shown in a dialog on return to ScienceDirect. ... Please enable JavaScript to use all the features on this page. ... Potassium 2,4-pentanedionate reacts with diazosulfides (E)-1 and (Z)-2 in DMSO to give 3-aryl-2,4-pentanediones 3 via an S RN 1 process. Advantages and drawbacks of such new access to 3 are reported together with relevant mechanistic implications.