Asymmetric Hydrosilylation of 1-Alkenes Catalyzed by Palladium-MOP.

Y Uozumi, K Kitayama, T Hayashi, K Yanagi…

Index: Uozumi, Yasuhiro; Kitayama, Kenji; Hayashi, Tamio; Yanagi, Kazunori; Fukuyo, Emiko Bulletin of the Chemical Society of Japan, 1995 , vol. 68, # 3 p. 713 - 722

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Citation Number: 89

Abstract

Asymmetric hydrosilylation of simple terminal alkenes (RCH= CH 2) with trichlorosilane at 40° C in the presence of 1× 10− 3 or 1× 10− 4 molar amounts of palladium catalyst prepared in situ from [PdCl (η 3-C 3 H 5)] 2 and (S)-2-diphenylphosphino-2′-methoxy-1, 1′- binaphthyl ((S)-MeO-MOP) proceeded with unusual regioselectivity and with high enantioselectivity to give high yields of 2-(trichlorosilyl) alkanes together with a minor ...