Deoxygenation of Some α-Dicarbonyl Compounds by Tris (diethylamino) phosphine in the Presence of Fullerene C60

IP Romanova, AV Bogdanov, VF Mironov…

Index: Griffiths, D. Vaughan; Griffiths, Penelope A.; Whitehead, Belinda J.; Tebby, John C. Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1992 , # 4 p. 479 - 484

Full Text: HTML

Citation Number: 21

Abstract

... J. Org. ... C═O (C 2 , 169.09 ppm) and between the H4 and sp 3 carbon (C 3 , 42.08 ppm) led us to conclude that for 13 the addend linkage to the fullerene sphere is in the C 3 position and not at C 2 . An almost perfect correlation of the calculated (GIAO B3LYP/6-31G(d)//HF/6 ...